Azido miristiko: berrikuspenen arteko aldeak

Azido miristiko
Formula kimikoa	C14H28O2
SMILES kanonikoa	2D eredua
MolView	3D eredua
Konposizioa	oxigeno eta karbono
Base konjokatua	tetradecanoate (en)
Eponimoa	Miristika
Mota	straight chain fatty acids (en) , long chain fatty acid (en) eta myristic acids (en)
Ezaugarriak
Dentsitatea	0,8622 g/cm³
Fusio-puntua	55 °C ; 53,96 °C
Irakite-puntua	326,2 °C
Masa molekularra	228,209 Da
Erabilera
Elkarrekintza	Free fatty acid receptor 1 (en) eta Free fatty acid receptor 4 (en)
Arriskuak
NFPA 704	1 2 0
Identifikatzaileak
InChlKey	TUNFSRHWOTWDNC-UHFFFAOYSA-N
CAS zenbakia	544-63-8
ChemSpider	10539
PubChem	11005
Reaxys	508624
Gmelin	28875
ChEBI	242115
ChEMBL	CHEMBL111077
ZVG	493248
EC zenbakia	208-875-2
ECHA	100.008.069
CosIng	35442
MeSH	D019814
RxNorm	1356758
Human Metabolome Database	HMDB0000806
KNApSAcK	C00001228
UNII	0I3V7S25AW
KEGG	C06424
PDB Ligand	MYR

Nabigazio historia interaktiboa

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IkusizkoaWikitestua

Lerroan

18:13, 26 apirila 2020ko berrikusketa

Azido miristikoa edo Azido tetradekanoikoa kate ertaineko gantz-azido ase bat da, ${\ce {CH3(CH2)12COOH}}$ formula duena. Hamalau karbono ditu (14:0).

Mintzeko proteina integralak izango direnei itsasten zaie Golgi aparatuan eta proteina miristoilatuak bihurtzen dira. Hau ezinbestekoa da zelula mintzean behar duten tokian kokatu daitezen^[1].

Jatorria

Intxaur muskatuaren (Myristica fragrans) koipetan %75a azido miristikoa da eta hortik datorkio izena. Palma eta koko oliotan ere ugaria da. Giza esnetan lipidoen %8,6a hartzen du, behietan %8eta 14 artean^[2]. Lyon Playfair indietako britainiarrak aurkitu zuen 1841 urtean^[3].

Erreferentziak

↑ «Las proteínas van donde deben gracias a un proceso simple» www.madrimasd.org (Noiz kontsultatua: 2020-01-16).
↑ (Ingelesez) Beare-Rogers, J. L.; Dieffenbacher, A.; Holm, J. V.. (2001-01-01). «Lexicon of lipid nutrition (IUPAC Technical Report)» Pure and Applied Chemistry 73 (4): 685–744. doi:10.1351/pac200173040685. ISSN 1365-3075. (Noiz kontsultatua: 2018-11-18).
↑ (Ingelesez) Playfair, Lyon. (1841-02). «XX. On a new fat acid in the butter of nutmegs» The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 18 (115): 102–113. doi:10.1080/14786444108650255. ISSN 1941-5966. (Noiz kontsultatua: 2018-11-18).

Kanpo estekak

Datuak: Q422658
Multimedia: Myristic acid / Q422658

[1] «Las proteínas van donde deben gracias a un proceso simple» www.madrimasd.org (Noiz kontsultatua: 2020-01-16).

[2] (Ingelesez) Beare-Rogers, J. L.; Dieffenbacher, A.; Holm, J. V.. (2001-01-01). «Lexicon of lipid nutrition (IUPAC Technical Report)» Pure and Applied Chemistry 73 (4): 685–744. doi:10.1351/pac200173040685. ISSN 1365-3075. (Noiz kontsultatua: 2018-11-18).

[3] (Ingelesez) Playfair, Lyon. (1841-02). «XX. On a new fat acid in the butter of nutmegs» The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science 18 (115): 102–113. doi:10.1080/14786444108650255. ISSN 1941-5966. (Noiz kontsultatua: 2018-11-18).

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@@ 1. lerroa: / 1. lerroa: @@
+{{konposatu kimiko infotaula}}
-{{chembox
-| Verifiedfields = changed
-| Watchedfields = changed
-| verifiedrevid = 396344370
-| Reference =
-| ImageFile = Myristic acid.svg
-| ImageSize =
-| ImageName = Skeletal formula of myristic acid
-| ImageFile1 = Myristic-acid-3D-balls.png
-| ImageSize1 =
-| ImageName1 = Ball-and-stick model of myristic acid
-| IUPACName = Azido tetradekanoikoa
-| OtherNames = C14:0 ([[Lipid number]]s)
-|Section1={{Chembox Identifiers
-| IUPHAR_ligand = 2806
-| CASNo_Ref = {{cascite|correct|CAS}}
-| CASNo = 544-63-8
-| UNII_Ref = {{fdacite|changed|FDA}}
-| UNII = 0I3V7S25AW
-| PubChem = 11005
-| ChEBI_Ref = {{ebicite|changed|EBI}}
-| ChEBI = 28875
-| ChEMBL_Ref = {{ebicite|changed|EBI}}
-| ChEMBL = 111077
-| SMILES = CCCCCCCCCCCCCC(=O)O
-| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
-| ChemSpiderID = 10539
-| InChI = 1/C14H28O2/c1-2-3-4-5-6-7-8-9-10-11-12-13-14(15)16/h2-13H2,1H3,(H,15,16)
-| InChIKey = TUNFSRHWOTWDNC-UHFFFAOYAZ
-| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
-| StdInChI = 1S/C14H28O2/c1-2-3-4-5-6-7-8-9-10-11-12-13-14(15)16/h2-13H2,1H3,(H,15,16)
-| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
-| StdInChIKey = TUNFSRHWOTWDNC-UHFFFAOYSA-N
-| RTECS = QH4375000
-| EINECS = 208-875-2
- }}
-|Section2={{Chembox Properties
-| C=14 | H=28 | O=2
-| Appearance =
-| Density = 1.03 g/cm<sup>3</sup> (−3&nbsp;°C)<br/> 0.99 g/cm<sup>3</sup> (24&nbsp;°C)
-| MeltingPtC = 54.4
-| MeltingPt_notes =
-| BoilingPtC = 326.2
-| BoilingPt_notes = at 760 mmHg<br/> {{convert|250|C|F K}}<br/> at 100 mmHg<br/> {{convert|218.3|C|F K}}<br/> at 32 mmHg
-| Solubility = 13 mg/L (0&nbsp;°C)<br/> 20 mg/L (20&nbsp;°C)<br/> 24 mg/L (30&nbsp;°C)<br/> 33 mg/L (60&nbsp;°C)
-| SolubleOther = Soluble in [[alcohol]], [[acetate]]s, [[benzene|C<sub>6</sub>H<sub>6</sub>]], [[haloalkane]]s, [[phenyl group|phenyls]], [[nitro compound|nitros]]
-| Solubility1 = 2.75 g/100 g (0&nbsp;°C)<br /> 15.9 g/100 g (20&nbsp;°C)<br/> 42.5 g/100 g (30&nbsp;°C)<br/> 149 g/100 g (40&nbsp;°C)
-| Solvent1 = azetona
-| Solubility2 = 6.95 g/100 g (10&nbsp;°C)<br/> 29.2 g/100 g (20&nbsp;°C)<br/> 87.4 g/100 g (30&nbsp;°C)<br/> 1.29 kg/100 g (50&nbsp;°C)
-| Solvent2 = bentzenoa
-| Solubility3 = 2.8 g/100 g (0&nbsp;°C)<br/> 17.3 g/100 g (20&nbsp;°C)<br /> 75 g/100 g (30&nbsp;°C)<br /> 2.67 kg/100 g (50&nbsp;°C)
-| Solvent3 = metanola
-| Solubility4 = 3.4 g/100 g (0&nbsp;°C)<br/> 15.3 g/100 g (20&nbsp;°C)<br/> 44.7 g/100 g (30&nbsp;°C)<br/> 1.35 kg/100 g (40&nbsp;°C)
-| Solvent4 = etil azetatoa
-| Solubility5 = 0.6 g/100 g (−10&nbsp;°C)<br/> 3.2 g/100 g (0&nbsp;°C)<br/> 30.4 g/100 g (20&nbsp;°C)<br/> 1.35 kg/100 g (50&nbsp;°C)
-| Solvent5 = toluenoa
-| Viscosity = 7.2161 cP (60&nbsp;°C)<br/> 3.2173 cP (100&nbsp;°C)<br/> 0.8525 cP (200&nbsp;°C)<br/> 0.3164 cP (300&nbsp;°C)
-| LogP = 6.1
-| RefractIndex = 1.4723 (70&nbsp;°C)
-| VaporPressure = 0.01 kPa (118&nbsp;°C)<br/> 0.27 kPa (160&nbsp;°C)<br/> 1 kPa (186&nbsp;°C)
-| ThermalConductivity = 0.159 W/m·K (70&nbsp;°C)<br/> 0.151 W/m·K (100&nbsp;°C)<br/> 0.138 W/m·K (160&nbsp;°C)
-| MagSus = -176·10<sup>−6</sup> cm<sup>3</sup>/mol
-  }}
-|Section3={{Chembox Structure
-| CrystalStruct = [[monoclinic crystal system|Monoclinic]] (−3&nbsp;°C)
-| SpaceGroup = P2<sub>1</sub>/c
-| PointGroup =
-| LattConst_a = 31.559&nbsp;Å
-| LattConst_b = 4.9652&nbsp;Å
-| LattConst_c = 9.426&nbsp;Å
-| LattConst_alpha =
-| LattConst_beta = 94.432
-| LattConst_gamma =
-  }}
-|Section4={{Chembox Thermochemistry
-| DeltaHc = 8675.9 kJ/mol{{nist|name=Tetradecanoic acid|id=C544638|access-date=17 June 2014|mask=FFFF|units=SI}}
-| HeatCapacity = 432.01 J/mol·K
-| DeltaHf = −833.5 kJ/mol
-  }}
-|Section7={{Chembox Hazards
-| GHSPictograms = {{GHS07}}
-| GHSSignalWord = Warning
-| HPhrases = {{H-phrases|315}}
-| FlashPt = >
-| FlashPtC = 110
-| FlashPt_notes =
-| NFPA-H = 2
-| NFPA-F = 1
-| NFPA-R = 0
-| NFPA_ref =
-| LD50 = >10 g/kg (rats, oral)
-  }}
-|Section8={{Chembox Related
-| OtherCompounds = [[Azido tridekanoiko]]a, [[Azido pentadekanoiko]]a
- }}
-}}
 '''Azido miristikoa''' edo '''Azido tetradekanoikoa''' kate ertaineko [[gantz-azido]] ase bat da, <chem>CH3(CH2)12COOH</chem> formula duena. Hamalau karbono ditu (14:0).